Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips
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چکیده
s Ruthenium Supramolecular chemistry Cage compounds ridyl)p
منابع مشابه
Ruthenium porphyrin compounds for photodynamic therapy of cancer.
Five 5,10,15,20-tetra(4-pyridyl)porphyrin (TPP) areneruthenium(II) derivatives and a p-cymeneosmium and two pentamethylcyclopentadienyliridium and -rhodium analogues were prepared and characterized as potential photosensitizing chemotherapeutic agents. The biological effects of all these derivatives were assessed on human melanoma tumor cells, and their cellular uptake and intracellular localiz...
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2-Aminopurine (Ap) modified human telomere sequences were used to monitor the specific complex formation of the G-quadruplex and 5,10,15,20-tetrakis(N-methyl-4-pyridyl)porphyrin (TMPyP4).
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Charge transport in a porphyrin with four identical pyridyl substituents, 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (TPyP), was investigated using the scanning tunneling microscopy break junction method. To determine the dominant pathway, we studied two structurally similar porphyrins, o-DPyP and p-DPyP. Our experiments reveal that charge transport through TPyP in a break junction configurat...
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The inhibition of the corrosion of N80 steel in 3.5 wt. % NaCl solution saturated with CO2 by four porphyrins, namely 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphyrin (HPTB), 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphyrin (T4PP), 4,4',4″,4‴-(porphyrin-5,10,15,20-tetrayl)tetrakis(benzoic acid) (THP) and 5,10,15,20-tetraphenyl-21H,23H-porphyrin (TPP) was studied using electrochemical impedan...
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